Copper-catalyzed aerobic oxidative synthesis of aryl nitriles from benzylic alcohols and aqueous ammonia.
نویسندگان
چکیده
Copper-catalyzed direct conversion of benzylic alcohols to aryl nitriles was realized using NH3(aq.) as the nitrogen source, O2 as the oxidant and TEMPO as the co-catalyst. Furthermore, copper-catalyzed one-pot synthesis of primary aryl amides from alcohols was also achieved.
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 11 20 شماره
صفحات -
تاریخ انتشار 2013